| Vermaas | Hendrik C W | | Member of the late Legislative Assembly, Transvaal. Member of the Union House of Assembly.
541 of 580 awards | Unknown |
| Vermooten | Octavius S | | Member of the late House of Assembly, Cape of Good Hope
542 of 580 awards | Unknown |
| Vernon | K V | | Clerk, Colonial Office
543 of 580 awards | Unknown |
| Viljoen | Antonie G | | Member of the late House of Assembly, Cape of Good Hope
544 of 580 awards | Unknown |
| Vintcent | Alwyn I | | Member of the Union House of Assembly.
545 of 580 awards | Unknown |
| Visser | Andreas G | | Member of the late House of Assembly, Cape of Good Hope
546 of 580 awards | Unknown |
| Von Hugell | N G | Lt Col | RE. CRE, Potchefstroom
547 of 580 awards | Royal Engineers |
| Vosloo | Johannes A | | Member of the late House of Assembly, Cape of Good Hope. Member of the Union House of Assembly.
548 of 580 awards | Unknown |
| Wales | A T G | Lt Col | Staff Officer, Natal Volunteers
549 of 580 awards | Staff |
| Walker | Alex H | | Member of the late Legislative Assembly, Natal
550 of 580 awards | Unknown |
| Walton | Edgar H | | Member of the late House of Assembly, Cape of Good Hope
551 of 580 awards | Unknown |
| Wannenburg | Petrus J | | Member of the late Legislative Assembly, Transvaal
552 of 580 awards | Unknown |
| Warden | L H | Lt Col | OC.1st Wiltshire Regiment
553 of 580 awards | (Duke of Edinburgh's) Wiltshire Regiment |
| Warren | William J | Colonel | Member of the late House of Assembly, Cape of Good Hope
554 of 580 awards | Unknown |
| Watermeyer | Egidius B | | Member of the late House of Assembly, Cape of Good Hope. Member of the Union House of Assembly.
555 of 580 awards | Unknown |
| Watkins | Arnold H | | Member of the Union House of Assembly.
556 of 580 awards | Unknown |
| Watt | Thos | | Member of the late Legislative Assembly, Natal. Member of the Union House of Assembly.
557 of 580 awards | Unknown |
| Weeber | Peter J | | Member of the late Legislative Council, Cape of Good Hope. Member of the Union Senate.
558 of 580 awards | Unknown |
| Weighton | John | Lt Col | OC Natal Carbineers
559 of 580 awards | Natal Carbineers |
| Wemys | Rosslyn E | Commodore | RN. In Command of HMS Balmoral Castle
560 of 580 awards | Royal Navy |
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