| Sauer | Mrs | | Wife of J Sauer
441 of 580 awards | Unknown |
| Saunders | Edward J A | | Member of the late Legislative Assembly, Natal
442 of 580 awards | Unknown |
| Scheiner | Theophilus L | | Member of the Union House of Assembly.
449 of 580 awards | Unknown |
| Schimper | Frans A S | | Member of the late Legislative Council, Orange River Colony
443 of 580 awards | Unknown |
| Schmidt | R | Corvetten Kapitan | Imperial German Navy, SMS "Sperber". Official representative at the opening of the Union Parliament
444 of 580 awards | Unknown |
| Schoeman | Johannes H | | Member of the late House of Assembly, Cape of Good Hope. Member of the Union House of Assembly.
445 of 580 awards | Unknown |
| Schofield | James | | Member of the late Legislative Assembly, Natal
446 of 580 awards | Unknown |
| Scholtz | P E | | Member of the late Legislative Assembly, Orange River Colony
447 of 580 awards | Unknown |
| Schreiner | Mrs W P | | Wife of William Schreiner
451 of 580 awards | Unknown |
| Schreiner | S C Cronwright | | Member of the late House of Assembly, Cape of Good Hope
448 of 580 awards | Unknown |
| Schreiner | William P | | Ex-PM of Cape Colony, Member of the Union Senate.
450 of 580 awards | Unknown |
| Schweizer | Constantine A | | Member of the late Legislative Council, Cape of Good Hope
452 of 580 awards | Unknown |
| Scobell | Henry J | Maj Gen | Commanding, Cape of Good Hope District
453 of 580 awards | Staff |
| Searle | Chas | | Member of the late House of Assembly, Cape of Good Hope. Member of the Union Senate.
454 of 580 awards | Unknown |
| Searle | Jas | | Member of the late House of Assembly, Cape of Good Hope. Member of the Union House of Assembly.
455 of 580 awards | Unknown |
| Searle | Thos | | Member of the late House of Assembly, Cape of Good Hope
456 of 580 awards | Unknown |
| Seely | J E B | Colonel | Parliamentary Under Secretary of State for the Colonies
457 of 580 awards | Unknown |
| Selborne | The Earl | | Late High Commissioner for South Africa
458 of 580 awards | Unknown |
| Sellar | John N | | Member of the late Legislative Assembly, Transvaal
459 of 580 awards | Unknown |
| Serfontein | Daniel J | | Member of the late Legislative Assembly, Orange River Colony. Member of the Union House of Assembly.
460 of 580 awards | Unknown |
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