| Southey | Charles | | Member of the Union Senate.
481 of 580 awards | Unknown |
| Sprigg | J Gordon | | Ex-Prime Minister of Cape Colony
482 of 580 awards | Unknown |
| Squibb | John D | Lt Col | OC Transvaal Scottish
483 of 580 awards | Unknown |
| Standford | William | Lt Col | OC Duke of Connaughts' Own Cape Town Highlanders.
484 of 580 awards | Cape Town Highlanders |
| Stanford | Walter E M | Colonel | Member of the late House of Assembly, Cape of Good Hope. Member of the Union Senate.
485 of 580 awards | Unknown |
| Stanley | Herbert J | | Private Secretary to HE The Governor General
486 of 580 awards | Unknown |
| Stapleton-Cotton | R G A W | Commander | RN. Late HMS Balmoral Castle
487 of 580 awards | Royal Navy |
| Start | Sydney Philip | Lieut | RN. Engineer Late HMS Balmoral Castle
488 of 580 awards | Royal Navy |
| Stewart-Bam | Pieter C Van B | Captain | Member of the late House of Assembly, Cape of Good Hope
489 of 580 awards | Unknown |
| Steyl | Johannes P G | | Member of the late Legislative Assembly, Orange River Colony. Member of the Union House of Assembly.
490 of 580 awards | Unknown |
| Steyn | D W | | Member of the late Legislative Assembly, Orange River Colony
491 of 580 awards | Unknown |
| Steyn | J W G | | Member of the late Legislative Council, Orange River Colony
492 of 580 awards | Unknown |
| Steyn | Martinus T | | Delegate to the National Convention. Ex-President of the Orange Free State.
493 of 580 awards | Unknown |
| Steyn | Mrs M T | | Wife of M Steyn
494 of 580 awards | Unknown |
| Steytler | A I | Rev | Moderator of the Dutch Reformed Church
495 of 580 awards | Unknown |
| Steytler | George L | | Member of the late Legislative Assembly, Orange River Colony. Member of the Union House of Assembly.
496 of 580 awards | Unknown |
| Stockenstrom | Andries | | Member of the late Legislative Assembly, Transvaal
498 of 580 awards | Unknown |
| Stockenstrom | Gysbert H | | Member of the late Legislative Council, Cape of Good Hope
497 of 580 awards | Unknown |
| Strachan | R | | Member of the late Legislative Assembly, Transvaal
499 of 580 awards | Unknown |
| Strauss | Jacobus G L | | Member of the late House of Assembly, Cape of Good Hope
500 of 580 awards | Unknown |
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